by adam89 » Sun Jun 09, 2013 10:04 pm
Anything over 50% will light to a naked flame. The idea is there is more alcohol than water content. That is where the 100 proof scale comes in. I can't comment on the Sambuca, I've never tried. But in theory if its less than 50% it shouldn't.
I've tried 40% saturated on wood and eventually it did light. I'm guessing this is because it got hot enough and it had a "wick" for the fuel to light on.