Oak and it effect on matrurturation

[Icarus]

There is an article on Tony Acklands Site (homedistiller.org) about the composition of oak and the effect of various components on alcohol during the maturation and aging processes.

The link to the article is as per below.

http://homedistiller.org/oak.pdf

cheers, Icarus

[grumpthehermit]

I found this page also,

Reading up to get a better understanding of what the timber / charring does for flavours.

:razz:

http://www.whiskeywise.com/whiskey-barrels.html

Cut and pasted here -

Whiskey barrels - Oak gives real character to the Whiskey

Whiskey barrels and the interaction between the oak and the whiskey and is one of the most interesting, if not completely understood components of the whiskey production process.


The quality of the Whisky barrels is carefully monitored because the new spirit is to gain character and colour from the wood in which it rests.

Some casks will previously have been used to mature oloroso, fino or amontillado sherries; some will have contained bourbon and some will be oak.

The type of Whiskey barrel used for maturation will have been determined by the Master Blender who is seeking a particular character and continuity of the whiskey.

Only after a minimum of three years maturation can the new make spirit be legally defined as Scotch Whisky.

In practice, most Scotch Whisky matures for much longer - from five to fifteen, twenty, or twenty-five years and sometimes longer.

It is this lingering period during which Scotland’s cool, clean air steals through the porous oak of the casks and charms their contents, contributing further to the smooth and golden character of each distillery’s unique creation.

A proportion of the whiskey in each cask evaporates annually and is lost to the heavens. This is known as the "angels’ share".

Why Oak?

One of the most frequently asked questions is “Why do whiskey makers use Oak Whiskey barrels?”
The reason that Oak is utilized is its unique physical and chemical nature. Oak has strength - physically, its wide radial rays give strength when shaped for a cask;

Oak is also a "pure wood" as opposed to pine or rubber trees which contain resin canals that can pass strong flavors to maturing whisky.

But it’s not just the Oak itself, it’s the transformation that happens to the Oak as a result of the seasoning and heating treatments during the coopering process - these result in the production of pleasant-tasting Oak lactones.

Whiskey barrels made from Oak have three broad effects on the spirit:

As an additive - It adds to the taste and aroma of the spirit by providing desirable elements from the cask. For example: vanillin, Oak lactone (coconut, bourbon character), toastiness, wood sugars and color.

As an agent that removes undesirable elements from new make spirit. For example: sulphur compounds and immaturity.

Oak barrels also interacts with the spirit. It adds extractive wood elements from the cask and converts them to organoleptically desirable elements.

For example it will change tannins to acetals, and change acetic acid to fruity esthers.

It has been said that there are 5 specific constituents of Oak and identifies how they influence maturing spirit:

Cellulose - Which has virtually no effect other than to hold the wood together.

Hemicellulose - Which consists of simple sugars that break down when heated and provide:

Body: through the addition of wood sugars

"Toasty & carmelised aromas & flavors"

Colour (unaged or "new make" whisky is a clear liquid)

Lignin - The binding agent that hold the cellulose in wood together which, when heated yield:

Vanillin

Sweet, smoky and spice aromas

Oak Tannins* - Which play an essential role in maturation by enabling oxidation and the creation of delicate fragrance in spirits. Tannins combine with oxygen and other compounds in the spirit to form acetals over time.

*Naturally occurring preservative compounds with a slightly puckery, astringent taste in the mouth, similar to the effect of strong black tea or fresh walnuts.

Oak Lactones - Resulting from lipids in the Oak, they increase dramatically during toasting and charring and can pass on a strong woody and perhaps coconut character; lactones give bourbon its distinctive character; and occur in higher concentrations in American Oak than in European varieties.

Will any Oak Whiskey barrel do?

Just three species of oak are used for wine and whisky barrel making or cooperage:
Quercus Alba, “White Oak” (America). Commonly referred to as “American Oak” and is the most commonly used variety in whisky cooperage.

More vanillin than European varieties Fast growth High in lactones, which when toasted, provide woody, vanilla, and coconut flavors

Quercus Petraea, “Sessile Oak” (Europe). Found across Europe, notably in France. Most commonly used for wine cooperage.

Slow growth, fine tannins and more vanilla (compared to Pedunculate)

Most common species in Tronçais forest

Quercus Robur, “Pedunculate Oak” (Europe). Found across Europe.

Spanish Oak generates more raisin, prune-like flavors.

Most commonly used for cognac and sherry cooperage.

Fast growth, more tannins, thus more oxidative characteristics in the matured products (compared to Sessile).

Most common species in Limousin forest

There are a number of other factors in how wood affects whisky. Chief among them are:

- Growth rate of the "donor trees";

- Method and length of time to dry the wood;

- Toasting and charring during cooperage.

Impact of Oak Growth Rate: Slower is Better

Winemakers are convinced of the relationship between Oak growth rates and the flavor and quality of their wines; while in whiskey, this factor is not widely considered.
It is known that slow growth Oak used in the making of whiskey barrels has more of the “good stuff” - especially vanillins and Oak lactones. White Oak is "fast-growth."

Once the wood is cut, the method used to season (dry) the wood has a huge impact. The wood MUST be dried before being used to make Whiskey barrels - the drying process converts chemical compounds in the wood to more desirable types.

How the wood is dried and for how long has a direct impact on the quality of the spirit.

It's accepted that air seasoning is better than kiln drying (it reduces tannic astringency as well as releases more vanillin), yet, while the barrels used to age wine may be made of staves which have been air dried for as much as 24 months - most bourbon whiskey barrels are made from wood which has been kiln dried in a matter of weeks.

Why? Some distillers think that the method for drying the wood is only important for the first-fill of a spirit aged in a new cask, (e.g., wine or bourbon) and has little or no impact when maturing spirits in previously used casks - and of course, Scotch is aged in previously used casks.

The Importance of Heat

The application of heat is integral to the process of making the barrel - wood fibers behave much like plastic polymers - they want to be straight.
In order to bend the staves, they need to be heated. The straight staves are arranged inside a metal hoop and heated. I have heard that either an open flame or steam may be used. As they are heated they become more pliable and are shaped

- hoops of various diameters are added to each end - six in total

- which are hammered down, towards the middle. Each hoop is held in place by the pressure exerted by the staves as they try to straighten themselves. The whiskey barells are then toasted which caramelizes the wood sugars.

This is where the construction of bourbon whiskey barrels casks and sherry casks diverge.

Bourbon Casks

The Whiskey barrels, once formed, are charred - the inside of the cask is set on fire for a short period of time, which creates a black charred layer.
There are various levels of charring which will have different affects on the spectrum of compounds and flavors the Oak will impart to the maturing spirit: more vanillins, lactones, "toastiness," spice characters, and tannins.

Charring casks causes further transformation. Char (carbon) removes sulphur compounds and immaturity from new spirit. Bourbon Whiskey barrels are typically charred for 40 seconds to 1 minute, but some distilleries have experimented with charring times of up to 3-4 minutes.

The result of charring is dramatic changes on the surface - for example, wood sugars are caramelized, which will leech into the maturing spirit.

Sherry Barrels

Sherry casks are only toasted and not charred. The casks used to mature Oloroso are the most popular with the Scotch industry.
Sherry casks can be made of American Oak, but this is usually for Fino Sherries and are generally not used by the Scotch industry.

It's accepted that European Oak adds more flavor thanAmerican Oak - sherry cask matured whiskies tend to be more full-bodied than bourbon Whiskey barrels matured ones, and this is likely the result of the type of wood, just as much as the type previous liquid occupant.

More History

The wide-spread use of bourbon whiskey barrels is a fairly recent occurrence - a result of the difficulty in sourcing sherry casks during the Spanish civil war in the late 1930's.
Currently any where from 300,000 - 400,000 bourbon casks are acquired for use in the maturation of Scotch whisky - in contrast to only about 18,000 sherry casks.

Contrary to popular belief, very few whiskies are aged exclusively in bourbon barrels - most ex-bourbon aged malts are vatted with a (varying) percentage of whiskey which was aged in ex-sherry barrels.

Laphroaig, Glemorangie 10, Ardbeg 10, Glenlivet 12, are among those few "pure" ex-bourbon matured whiskies.

Barrel Sizes

There are three Whiskey barrel sizes commonly used by the Scotch whisky industry:
Barrels - 190 liters/50 gallons

Hogsheads - 250 liters/66 gallons

Butts - 500 liters/132 gallons

Butts come from the sherry industry while the majority of Whiskey barrels and hogsheads originate in the bourbon industry. All things being equal, the larger the cask the slower the maturation.

Conversely, a smaller cask means that the maturing whisky is exposed to more wood and maturation is quicker - the Laphroaig quarter cask is an example of this.

One last thing

Once a bourbon whiskey barrel has completed its "first life" that is, it has been used to age bourbon, it is ready for its second life as a whisky aging vessel.
It is broken back down into separate staves and shipped to Scotland. In Scotland, coopers reassemble the staves into casks which will be used to age the whiskey that you will enjoy in a few years. Some bourbon whiskey barrels and all sherry casks are generally shipped whole - not broken down into separate staves.

It's not common, but some companies re-char ex-bourbon whiskey barrels before use.

Casks may be used for as many as four fills, i.e., filled with four separate batches of new make spirit. Generally, though, casks are retired after their second, or third re-fills.

Sometimes when a whiskey barrel has reached the end of it's their useful life - after it has been filled and re-filled so many times that the spirit has taken out all the "good stuff" from the wood, some distillers will shave down the the inside of the cask to reach fresh wood and then the cask will be re-charred.

How ex-sherry casks are treated, once whiskey distillers get their hands on them, differs by distiller. Most will empty the cask of any residual sherry, nose the cask (to ensure the casks smells fresh, and then fill with new spirit.

Dave Robertson doesn't believe any one would char fresh sherry casks unless the sherry cask does not smell "right", in which case they might char, or may simply reject the cask.

Life after Whisky

The Whisky industry has found a novel way of re using the wood from the barrels that have reached the end of their lives.
Rather than throw them away a company called McKay Flooring from Glasgow have devised a system for making flat boards from the distinctive oak barrels that they turn into floor boards, many with the original branding and often with the hint of some unique and distinctive smells.

Whilst it looks great in a bar or lounge, it seems to be creating a fair level of interest from Whiskey enthusiasts who are considering putting what is a unique floor into their whisky drinking den or room.

What a stunning idea!

If you are interested in more information I suggest you use this link. Recycled Oak flooring using whiskey barrels

Cooperage Facts

Diogenes, the famous Greek philosopher, was reputed to have lived in a Whiskey barrel in Athens many years B.C. More likely it was a clay amphora of that time.
The Latin word cuparius is the root of our word cooper. The Romans had developed a high degree of technology in most things. Making barrels for storage of various goods, both dry and wet, is probably a skill they developed. However most archaeology indicates wine was stored and transported in clay amphorae.

Legend indicates that cooperage was a celtic invention. The vikings had developed the wood joint in boat making. The design of a barrel is on the double arch engineering principle, for strength. Being round it is also easy to move, and the chimb allows for lifting hooks.

Provisioning of ships for dry and wet goods seems to go hand in hand with whiskey barrels. The description "tonnage" refers to capacity, not weight.

Before Columbus chanced on America, there is no indication that barrels existed in either south or north America.

President Kennedy's great grandfather was an Irish cooper who emigrated to Boston during the potato famine. He became a publican.

The Virgin Mary was the Patron Saint of coopers in England until being dropped due to religious persecution in the 15th century.

Pinkerton, the famous detective, was a Glasgow cooper and Chartist who emigrated to America in 1850 on persecution grounds.

Cheers
GTH

[Frank]

:text-goodpost: thanks GTH
and the 'whiskeywise' site has some other interesting info links too.....

[crow]

:text-+1:

[grumpthehermit]

No Worries,

Glad you find it useful / interesting.

I stumbled across it and thought it a good read.

Cheers
GTH

[audistiller]

and the 'whiskeywise' site has some other interesting info links too.....

I second that, some very good reading there.